The Journal of Chemical Physics
A preliminary rotation‐vibration analysis of the n=0 and n=1 subbands associated with the nν6+ν1−nν6 hydrogen‐bonded vibration in HCN⋅⋅⋅HF has been completed. The following excited staterotational constantsB′ and band origin frequencies ν0 have been determined for the complex. The results are consistent with a rotation‐vibration interaction constant α1=−68.3±1 MHz which correlates with an excited stater(N⋅⋅⋅F) internuclear distance of 2.762 Å, a decrease of 0.034 Å relative to the ground state.Excited state lifetimes associated with assigned transitions are demonstrated to be ≥1.8×10− 1 0s while the x 1 6 anharmonic constant is evaluated to be 4.01±0.03 cm− 1.
Kyrö, E.; McMillan, K.; Eliades, M.; Danzeiser, D.; Shoja-Chaghervand, P.; Lieb, Shannon; and Bevan, J. W., "Preliminary Rovibrational Analysis of the nν6+ν1−nν6 Vibration in HCN⋅⋅⋅HF" The Journal of Chemical Physics / (1983): 5881-5885.
Available at https://digitalcommons.butler.edu/facsch_papers/779